Peking University has successfully prepared high-quality perovskite submicron single crystal material to realize continuous optical pumping laser source

Constructing a continuous laser source with a device area of less than 1 μm2 can meet the low energy requirements of on-chip optical interconnection (< 10 fJ bit−1) is of great significance. However, as the device size decreases, optical and material losses increase significantly, so achieving sub-micron device size and continuous optical pumping of laser sources is extremely challenging.

In recent years, halide perovskite materials have received extensive attention in the field of continuous optically pumped lasers due to their high optical gain and unique exciton polariton properties. The device area of perovskite continuous laser sources reported so far is still greater than 10 μm2, and submicron laser sources all require pulsed light with higher pump energy density to stimulate.

In response to this challenge, the research group of Zhang Qing from the School of Materials Science and Engineering of Peking University successfully prepared high-quality perovskite submicron single crystal materials to achieve continuous optical pumping laser sources with a device area as low as 0.65 μm2. At the same time, an anomalous threshold-size structure activity relationship in the photon-exciton strong coupling region is revealed, and the mechanism of exciton polariton in submicron continuous optically pumped lasing process is deeply understood, which provides a new idea for the development of small size and low threshold semiconductor lasers.

The results of the study, titled "Continuous Wave Pumped Perovskite Lasers with Device Area Below 1 μm2," were published in Advanced Materials on June 14, 2023.

In this work, the inorganic perovskite CsPbBr3 single crystal micron sheet was prepared on sapphire substrate by chemical vapor deposition. It was observed that the strong coupling of perovskite excitons with the sound wall microcavity photons at room temperature resulted in the formation of excitonic polariton. Through a series of evidences, such as linear to nonlinear emission intensity, narrow line width, emission polarization transformation and spatial coherence transformation at threshold, the continuous optically pumped fluorescence lase of sub-micron-sized CsPbBr3 single crystal is confirmed, and the device area is as low as 0.65 μm2. At the same time, it was found that the threshold of the submicron laser source is comparable to that of the large-size laser source, and can even be lower (Figure 1).

Both experimentally and theoretically, this work reveals the mechanism of excitonic polariton in the realization of submicron continuous laser sources. Enhanced photon-exciton coupling in submicron perovskites results in a significant increase in the group refractive index to about 80, which substantially increases the mode gain to compensate for the mode loss. This also results in a perovskite submicron laser source with a higher effective microcavity quality factor and a narrower emission linewidth (Figure 2). The mechanism also provides new insights into the development of small-size, low-threshold lasers based on other semiconductor materials.

Source: Sohu